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Entropic Attraction and Repulsion in Binary Colloids Probed with a Line Optical Tweezer

by: JC Crocker, JA Matteo, AD Dinsmore, AG Yodh
Physical Review Letters, Vol. 82, No. 21. (24 May 1999), 4352.


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weeks さんは全部で 0 非公開 + 1 公開 のメモを書いています.

journal club 5-17-02, 6-25-07

weeks (公開 ) - 2007-09-22 20:04:31

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The long-range entropic forces that arise between two micrometer-sized colloidal spheres in a fluid of much smaller colloidal spheres were directly measured using a line-scanned optical tweezer. This new technique allowed us to measure the functional form of the potential with sub- k B T energy and 15 nm spatial resolution. At the lowest small sphere concentrations; the potential was monotonically attractive; while at higher concentrations an oscillatory potential was observed; due to the liquid structure of the small spheres. Surprisingly; the large spheres came together only rarely at the higher concentrations; suggesting a new means for stabilizing suspensions using entropy alone.


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