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Organic small molecule solar cells with a homogeneously mixed copper phthalocyanine: C[sub 60] active layer

by: Soichi Uchida, Jiangeng Xue, Barry P Rand, Stephen R Forrest
Applied Physics Letters, Vol. 84, No. 21. (2004), pp. 4218-4220.


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An efficient organic solar cell with a vacuum codeposited donor–acceptor copper phthalocyanine (CuPc):C60 mixed layer is described. A device with a structure of indium tin oxide/330 Å CuPc:C60(1:1)/100 Å C60/75 Å 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline/Ag has a series resistance of only RS = 0.25   cm2, resulting in a current density of ~1 A/cm2 at a forward bias of +1 V, and a rectification ratio of 106 at ±1 V. Under simulated solar illumination, the short circuit current density increases linearly with light intensity up to 2.4 suns. The maximum power conversion efficiency is P = (3.6±0.2)% at 0.3 suns (AM1.5G simulated solar spectrum) and P = (3.5±0.2)% at 1 sun. Although the fill factor decreases with increasing intensity, a power efficiency as high as P = (3.3±0.2)% is observed at 2.4 suns intensity. ©2004 American Institute of Physics.


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